Physical chemistry and structural chemistry
A tantárgyleírás hatályossága
| Subject name (Hungarian, English) |
Fizikai kémia és kémiai anyagszerkezettan
Physical chemistry and structural chemistry
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| Subject code | BMEVEFAM201 | ||||||||||||
| Subject type | — | ||||||||||||
| Training Level | — | ||||||||||||
| Course types and hours (weekly/semester) |
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| Assessment type | vizsga | ||||||||||||
| Credits | 5 | ||||||||||||
| Subject coordinator |
Dr. Kubinyi Miklós János
contact:
kubinyi.miklos@vbk.bme.hu
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| Responsible department |
Fizikai Kémia és Anyagtudományi Tanszék
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| Faculty | Vegyészmérnöki és Biomérnöki Kar | ||||||||||||
| Subject website | http://oktatas.ch.bme.hu/oktatas/konyvek/fizkem/structural%20chemistry/ | ||||||||||||
| Primary curriculum type | — | ||||||||||||
| Direct prerequisites – Strong prerequisite | none | ||||||||||||
| Direct prerequisites – Weak prerequisite | none | ||||||||||||
| Direct prerequisites – Parallel prerequisite | none | ||||||||||||
| Direct prerequisites – Milestone prerequisite | none | ||||||||||||
| Direct prerequisites – Exclusion | none |
Objectives
1. Interactions of atoms and molecules with particles and external fields
1.1. Research and its application
1.2. Interactions with particles
1.3. Interactions with electric field
1.4. Interactions with magnetic field
1.4.1. Elementary magnets
1.4.2. Diamagnetism
1.4.3 Precession magnetic moment
1.4.4. Paramagnetism
1.5. Interactions with magnetic waves
1.6. The electromagnetic spectrum
2. Structure and properties of atoms
2.1. Introduction
2.2. The hydrogen atom
2.2.1. The structure of the hydrogen atom
2.2.2. Angular and magnetic moments of the hydrogen atom
2.2.3. Selection rules of the hydrogen atom
2.2.4. The electronic spectrum of the hydrogen atom
2.3. Many-electron atoms
2.3.1. Hydrogen-like atoms
2.3.2. Other many-electron atoms
2.3.3. Interaction with external magnetic field
2.3.4. Interaction with external electric field
2.3.5. Interpretation of the electronic spectra
2.3.6 The measurement of the atomic spectra
2.4. Ions
2.4.1. Ionization
2.4.2. Interactions of ions
3. Structure and properties of molecules
3.1. Molecular symmetry
3.1.1. Symmetry elements and symmetry operations
3.1.2. Point groups
3.1.3 Representations of point groups
3.2. The electronic structure of molecules
3.2.1. Construction of molecular orbitals
3.2.2. The symmetry of molecular orbitals
3.2.3. Localized molecular orbitals
3.3. The covalent bond
3.3.1. The characteristics of the covalent bond
3.3.2. The structure of two-atomic molecules
3.3.3. Hybridization
3.3.4. Delocalized systems
3.3.5. Complex compounds of the transition metals
3.4. The rotation of the molecules
3.4.1. Introduction
3.4.2. Rotational motion of diatomic molecules
3.4.3. The rotational spectra of the diatomic molecules
3.4.4 The rotational spectra of polyatomic molecules
3.5. The vibration of molecules
3.5.1. Vibrational motion of diatomic molecules
3.5.2. Vibrational spectra of diatomic molecules
3.5.3. Vibrations of polyatomic molecules
3.5.4. Vibrational spectra of polyatomic molecules
3.5.5. Non-linear spectroscopy
3.5.6. Other vibrational spectroscopic methods
3.5.7. Large amplitude motion
3.6. Electronic transitions in molecules
3.6.1. The excitation of the electrons
3.6.2. The types of electronic transitions
3.6.3. The excited state and its decay
3.6.4. The electron excitation spectrum and the substituent effect
3.6.5. Measurement and application of electron excitation spectra
3.6.6. Ultraviolet photoelectron spectroscopy (UPS)
3.7. The dispersion of light
3.7.1. The dispersion of the refractive index
3.7.2. Electron excitation with polarized light
3.8. Mass spectroscopy (MS)
3.8.1. The principle and instrumentation of mass spectroscopy
3.8.2. Applications of the mass spectroscopy
3.9. Paramagnetic properties of molecules
3.9.1. Paramagnetic molecules
3.9.2. Electron spin resonance
3.10. Nuclear magnetic resonance (NMR)
3.10.1. The nuclear magnetic resonance
3.10.2. Spin-spin interactions
3.10.3. 13C-NMR spectroscopy
3.10.4. Recording NMR spectra
3.10.5. The Overhauser effect (NOE)
3.10.6. Relaxation processes
3.10.7. Measurement of the relaxation processes
3.10.8. Two-dimensional NMR spectroscopy
3.11. Diffraction methods in the molecular structure elucidation
3.11.1 Introduction to the diffraction methods
3.11.2 Scatterings on isolated molecules
3.11.3 Electron diffraction in gas phase
3.11.4 The character of the measured and calculated geometric parameters
4. The structure of atomic and moleclar ensembles
4.1. Intermolecular interactions
4.1.1. The theoretical description of the intermolecular interactions
4.1.2 The types of intermolecular interactions
4.2. The structure of molecular ensembles
4.2.1. Liquid state models
4.2.2 The structure of liquids
4.2.3. The solid crystalline phase
4.2.4 Conductors, semiconductors and insulators in solid state
4.3. Diffraction methods
4.3.1. Diffraction methods in the structure investigation of ordered systems
4.3.2. Methods of X-ray diffraction
4.3.3. Methods of electron diffraction in solid state
4.3.4. Methods of neutron diffraction
4.4. Spectroscopic methods
4.4.1. X-ray photoelectron spectroscopy (XPS)
4.4.2. Auger-electron spectroscopy (AES)
4.4.3 Secondary ion emission mass spectrometry (SIMS)
4.4.4. Mössbauer spectroscopy
4.4.5. Vibrational spectroscopy in condensed phases
Learning outcomes
Ez a tantárgy a KKK rendeletben meghatározott, következő kompetenciák fejlesztését szolgálja:
Knowledge
Skills
Attitudes
Autonomy and responsibility
Oktatási módszertan
Tanulástámogató anyagok
Online források
Recommended preliminary knowledge for completing the subject
General rules
Assessment methods
In-term assessments
No detailed assessments provided.
Weight of in-term assessments
No weights provided.
Exam-period assessments
No detailed assessments provided.
Weight of exam elements
No weights provided.
Grade calculation
No grade thresholds provided.
Attendance requirements
No attendance requirements provided.
Rules for retake and resubmission
Not provided.
Short description
Not provided.
Detailed description
Recommended courses
Workload to complete the subject
No workload breakdown provided.
Validity of subject requirements
Curriculum placement
| Faculty | Program | Curriculum | Curriculum type | Primary |
|---|---|---|---|---|
| Vegyészmérnöki és Biomérnöki Kar | vegyészmérnöki | Vegyészmérnöki mesterképzési szak tanterve | kötelező | nem |
| Vegyészmérnöki és Biomérnöki Kar | vegyészmérnöki | Vegyészmérnöki mesterképzési szak tanterve | kötelező | nem |
| Vegyészmérnöki és Biomérnöki Kar | vegyészmérnöki | Vegyészmérnöki mesterképzési szak tanterve | kötelező | nem |
| Default Faculty | Default Program | Default Curriculum | — | nem |